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There is a video about this. saami ammunition fire video - Bing videoAmmunition is not likely to combust inside your safe, nor anywhere else. Even when ammo is burned in a fire, the fire is the problem not the ammo. Tests were done by the SAAMI (go to saami.org) decades ago (1974) to prove how safe ammo storage was, in response to laws being proposed in Chicago. SAAMI worked in conjunction with the Chicago Fire Prevention Bureau. They did the tests at the Olin Winchester Ammo Works in Alton IL. Published the works in 1977. You can read the results here:
Facts About Sporting Ammunition Fires - SAAMI