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Here is a thread on Arfcom some may be interested where an old 8# jug of powder self-combusted.

http://www.ar15.com/forums/topic.html?b=6&f=42&t=281373

On the otherhand, I opened a 1# canister of Unique last night that was given to me a few years ago. The old owner bought it at least 2 decades ago. The powder was black as coal and had no smell. I put a match to 5 grains worth and it went right up.

All 15 rounds of 45LC I loaded up shot great today.

BTW, the price tag on the canister is $5.60!
 

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