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Smokeless powder is by definition a propellent, whereby a comparative "push" is acting on the bullet. That is when a proper balance of bullet weight and diameter, cartridge capacity and the burning rate of the powder is provided to accellerate the projectile with appropiate pressure. So when that part of a loading "recipie" is wrong, ie. a powder with much too fast a burning rate is used, something closer to an explosion occurs,(an unsafe pressure spike) rather than a controlled burn to achieve a given velocity.
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